We obtain a four-photon polarization-entangled state with a visibility as high as (95.35\pm 0.45)% directly from a single down-conversion source. A success probability of (81.54\pm 1.38)% is observed by applying this entangled state to realize a four-party quantum communication complexity scenario (QCCS), which comfortably surpass the classical limit of 50%. As a comparison, two Einstein-Podolsky-Rosen (EPR) pairs are shown to implement the scenario with a success probability of (73.89\pm 1.33)%. This four-photon state can be used to fulfill decoherence-free quantum information processing and other advanced quantum communication schemes.
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